Saturday, 27 February 2016

What is the meaning of internal Energy?


What is the meaning of internal energy. Is it the amount of energy that a body contains?



Answer



Standard Definition : The internal energy of a system is identified with the random, disordered motion of molecules; the total (internal) energy in a system includes potential and kinetic energy.


Since this molecular motion is primarily a function of temperature, the internal energy is sometimes called 'thermal energy'.


Total energy of the system $(E)$ = U (Thermal energy) + $E_{Kinetic\space of\space system}$ + $E_{Potential\space of\space system}$ ....



Here, the two terms viz, $E_{Kinetic\space of\space system}$ and $E_{Potential\space of\space system}$, are for the system and not the particles inside the system. For the particles the $KE$ and $PE$ is included in the internal energy.


In most of the cases, kinetic energy, potential energy, chemical energy of the system is constant, thus we conclude,


$\Delta{E}=\Delta{U}$


The proper form of the first law of thermodynamics is given by,


$\Delta E = q + W$,


but for the reasons stated above,


$\Delta U = q + W$.


Therefore, summing it up, Internal energy includes :


1). Translational KE


2). Vibrational and rotational kinetic energy



3). Potential energy from intermolecular forces


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