Monday, 21 September 2015

quantum mechanics - What is the most general expression for the coordinate representation of momentum operator?



I have a question about deriving the coordinate representation of momentum operator from the commutation relation, $[x,p]= i$.


One derivation (ref W. Greiner's Quantum Mechanics: An Introduction, 4th edi, p442) is as following: $$ \langle x|[x,p]|y \rangle = \langle x|xp-px|y \rangle = (x-y) \langle x|p|y \rangle. $$ On the other hand, $ \langle x|[x,p]|y \rangle = i \langle x|y \rangle = i \delta (x-y)$. Thus $$ (x-y) \langle x|p|y \rangle = i \delta(x-y). \tag{1} $$


We use $(x-y) \delta(x-y) = 0$. Take the derivative with respect to $x$; we have $\delta(x-y) + (x-y) \delta'(x-y) = 0$. Thus $$ (x-y) \delta'(x-y) = - \delta(x-y). \tag{2} $$


Comparing Eqs. (1) and (2), we identify $$ \langle x|p|y \rangle = -i \delta'(x-y). \tag{3} $$


In addition, we can add $\alpha \delta(x-y)$ on the right-hand side of Eq. (3), i.e. $$ \langle x|p|y \rangle = -i \delta'(x-y) + \alpha \delta(x-y), $$ and $[x,p] = i$ is still satisfied. We can also add $$ \frac{\beta}{\sqrt{|x-y|}}\delta(x-y)$$ on the RHS of Eq. (3). Here $\alpha$ and $\beta$ are two real numbers.


My question is, what is the most general expression of $\langle x|p|y \rangle$? Can we always absorb the additional term into a phase factor like Dirac's quantum mechanics book did?


Thank you very much in advance.



Answer



We start by mentioning a couple of standard formulas


$$\tag{1} \psi(x)~=~\langle x | \psi \rangle, $$



and


$$\tag{2} \langle x | y \rangle ~=~\delta(x-y).$$


The canonical commutation relation (CCR) is


$$\tag{3} [\hat{x}, \hat{p}] ~=~i\hbar{\bf 1}. $$


The standard Schrödinger position representation reads


$$\tag{4}\hat{x}~=~x, \qquad \hat{p}~=~-i\hbar\frac{\partial}{\partial x}.$$


We may conjugate the standard Schrödinger position representation (4) by an unitary operator $\hat{U}=e^{-if(\hat{x})}$, where $f:\mathbb{R}\to\mathbb{R}$ is a given differentiable function. In this way we obtain an unitary equivalent position representation


$$\tag{5}\hat{x}~=~x, \qquad \hat{p} ~=~-i\hbar e^{-if(x)}\frac{\partial}{\partial x}e^{if(x)} ~=~-i\hbar\frac{\partial}{\partial x}+ \hbar f^{\prime}(x),$$


of the CCR (3). The standard Schrödinger position representation (4) corresponds to $f\equiv {\rm const}$. For a general irreducible representation of the CCR (3), see the Stone-von Neumann Theorem.


The representation (5) implies



$$\tag{6} \langle x | \hat{p} |\psi \rangle~=~(\hat {p} \psi)(x) ~=~-i\hbar e^{-if(x)}(e^{if}\psi)^{\prime}(x) ~=~-i\hbar\psi^{\prime}(x)+ \hbar f^{\prime}(x)\psi(x). $$


From (6) we conclude that the momentum matrix elements reads


$$\tag{7} \langle x | \hat{p} |y \rangle~=~-i\hbar\delta^{\prime}(x-y)+ \hbar f^{\prime}(x)\delta(x-y)$$


in the representation (5).


Finally, here and here are two other Phys.SE posts that also discuss ambiguities in $x\leftrightarrow p$ overlaps.


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