in an online video lecture,(around 36min, where the exactly statement is at 36min33secs.) i got one question, suppose we have a system of N particles, {→ri(t)}i=1,⋅⋅⋅,N are the position vectors of the particles. I was told in the lecture that the so-called self intermediate scattering function is defined as. Fs(k,t)=1N⟨N∑i=1ei→k⋅[→ri(t)−→ri(0)]⟩. (for homogeneous system, it only depends on the absolute value of →k.)
Furthrmore, it is said by the lecturer that when k→0, Fs(k,t)→1N⟨N∑i=1[→ri(t)−→ri(0)]2⟩
but i can't see why. Could anybody give me some help on it.
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