Is there only one reversible way to move from one state to another?
If we consider two states $A$ and $B$ on an isotherm and we move from $A$ to $B$ by first reversible isochoric process and then reversible isobaric process. Now the path followed should be reversible since both the processes were reversible. But what about simply following the reversible isothermal process?
According to me both processes should be reversible. Now entropy is the heat added reversibly to move from one state to another divided by the temperature at which it is added. But we know that the heat added to the system is different in both the cases. Then how is entropy a state function?
Answer
The total heat added in both the processes is different. Infinitesimal change in entropy is defined as $\int(dQ/T)$. Along the isotherm, the temperature remains constant. But along the other two reversible processes you have mentioned, the temperature is not constant. Effectively, it can be seen by integration that change in entropy in both processes is the same.
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