optics - Wavelength-dependent refractive index

I read in a book about optical fibers that the different spectral components of a light pulse transmitted in the fiber propagate with different velocities due to a wavelength dependent refractive index. Can someone explain that? Why is that silica refractive index depends on the wavelength/frequency of the wave?

Answer

The fundamental reason for the wavelength dependance of refractive index ($n$), in fact the fundamental description of refraction itself, is the domain of quantum field theory and is beyond my understanding. Hopefully somebody else can provide an answer on that subject.

However, I can state that it isn't just silica that has a wavelength dependent $n$. In fact, every material has some wavelength dependence, and this property is called dispersion. In optical materials, the dispersion curve is very well approximated by the Sellmeier Equation: $$n^2(\lambda) = 1 + \sum_k \frac{B_k \lambda^2}{\lambda^2 - C_k}$$

usually taken to $k=3$, where $B_k$ and $C_k$ are measured experimentally. As far as I know this equation is not derived from theory; it is completely empirical.