The Hamiltonian
H=[a00−b00−b00−b00−b00−a]
commutes with the qubit exchange operator
P=[1000001001000001]
So I would expect the two to have the same eigenvectors. The eigenvectors of P are easily seen to be (1,0,0,0)T;(0,0,0,1)T;(0,1,1,0)T;(0,1,−1,0)T. The latter two are also eigenvectors of H, but the first two are not. Why? I thought commuting operators shared the same eigenbasis?
Answer
Call u1,u2,u3,u4 the eigenvectors described by you, respectively. Your claims are all right, but realize that both u1 and u2 share the same eigenvalue, that is 1, i.e., Pu1=u1 and Pu2=u2. Hence, any linear combination of u1 and u2 will also be eigenvectors with the same eigenvalue 1. Try to find eigenvectors of H of the form αu1+βu2, with α and β being constants.
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