How can I convince myself that wavefunctions of electrons on molecular orbitals are indeed standing waves?
Is it a consequence of the fact that electrons don't drift away from the molecule?
In other words, can one prove from the Schrödinger equation that, unless ψ(x,t) can be represented as ϕ(x)θ(t), then limt→∞∫U|ψ(ˉx,t)|2dˉx=0 for any bounded set U⊂R3 (or something along those lines)?
Or are there physical considerations that explain the standing waves?
Update. Apparently «standing wave» is an ambiguous/controversial term here, so let me reformulate my question in a more mathematical and unambiguous way without referring to standing waves.
Let a wavefunction ψ correspond to a stationary state, i.e. |ψ(x,t)|=const(t). We can conclude, then, that ψ(x,t)=ϕ(x)θ(x,t), where |θ(x,t)|=1. In order to separate the variables and move on to the time-independent Schrödinger equation, we also need to establish that θ(x,t) doesn't depend on x. Where does this assumption follow from?
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