There is a coupling in the standard model of the form θFμν˜Fμν where Fμν is the QCD field strength. I've read that θ<10−8, which is speculated to be related to Peccei-Quinn symmetry.
What would be the consequences of this term if θ were not small? In particular, I know that this term is CP-violating. How will this CP-violation be manifested in experiments?
How do we know θ<10−8?
Answer
To answer point 2, θ is derived from the neutron elecric dipole moment that is measured to be like <10−18e⋅m. You can prove that the dipole moment is proportional to θ and from that you can get your upper limit for θ. See Donoghue, Golowich, Holstein - "Dynamics of the Standard Model", pages 44-45 for more details.
As far as your first question is concerned, a value of θ different from 0 would make CP not a symmetry for QCD, but I don't really know what effect this could have in detail.
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