I’m a high school student and was recently studying basic statistical mechanics (for use in physical chemistry). In the derivation of the Boltzmann derivation or the partition function we arrive at a factor e−βT. So I searched for the connection of β to temperature and got one proof for that on the wikipedia site. But it seems to make to make the assumptions that
- The energy of a system in equilibrium depends only on the temperature.
- At equilibrium the number of microstates is maximized.
It uses the formula S=kln(W).
So I just wanted to know that which of the assumptions is an experimental fact and whether we can arrive at the equation S=kln(W) without already using β=1/(kBT) otherwise the proof would become circular.
To improvise, we can use the property of Lagrange multipliers to obain that β=d(ln(W))dT but I still don’t see how can we reach to the value of β from here.
P.S. I am just a beginner so please use simple language if possible.
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