Wednesday 6 March 2019

fluid dynamics - How is pressure an intensive property?


I've seen this question asked before but I can't find an answer to the specific point I'm troubled with. From the kinetic theory of gases, pressure results from molecules colliding with the walls of a container enclosing a gas, imparting a force upon the wall. Now, if we split the container into two halves, I am told that pressure remains the same on either side of the partition assuming the gas has uniform density throughout the container. But If we split the container into two, isn't there effectively half the number of molecules striking the wall on each side so the pressure should also be halved? Shouldnt pressure be dependent on the number of molecules?



Answer





If we split the container into two, isn't there effectively half the number of molecules striking the wall on each side so the pressure should also be halved? Shouldnt pressure be dependent on the number of molecules?



You are right that if we only halved the number of particles we would have a smaller pressure. But you have also halved the volume of the container. The fewer number of particles hits the walls more frequently due to the smaller volume. In other words, the number of particles goes down, but the number of collisions per particle goes up. The two effects cancel out, leading to the same pressure as before you put in the partition.


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