I was working through the operation of the time reversal operator on a spinor as was answered in this question, however, I cannot figure out how this step was done:
e−iπ2σy=−iσy.
I suspect it has something to do with a taylor series expansion. Here σy is the pauli matrix which has the form σy=(0−ii0).
Answer
The relation is shown using a taylor series of the exponential: ex=1+x+x22!+x33!+... so that e−iπ/2σy can be expanded.
e−iπ/2σy=1+(−iπ/2σy)+(−iπ/2σy)22!+(−iπ/2σy)33!+(−iπ/2σy)44!+(−iπ/2σy)55!+...
Noting that σ2y=(0−ii0)(0−ii0)=(1001)=I then
e−iπ/2σy=1−iσy(π/2)−(π/2)22!+iσy(π/2)33!+(π/2)44!−iσy(π/2)55!+...={1−(π/2)22!+(π/2)44!+...}−iσy{(π/2)−(π/2)33!+...}=cos(π/2)−iσysin(π/2)=−iσy
Here the taylor series for cos and sin were used to simplify the infinite sequence: cos(x)=1−x22!+x44!+... and sin(x)=x−x33!+x55!+...
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