Asking a question Has anyone tried to incorporate the electrons magnetic dipole moment into the atomic orbital theory?, I was curious whether anyone has attempted to relate the intrinsic property of the magnetic moment of the electron to the above-mentioned properties of spin.
In the extremely detailed answer (thanks to the author, who took the time despite the pointlessness of such a question) it is clarified that
The effects are weak, and they are secondary to all sorts of other interactions that happen in atoms,...
Also, in case you're wondering just how weak: this paper calculates the energy shifts coming from electron spin-spin coupling for a range of two-electron systems. The largest is in helium, for which the coupling energy is of the order of ∼7cm−1, or about 0.86meV, as compared to typical characteristic energies of ∼20eV, some five orders of magnitude higher, for that system.
Now there is a new question about Electron to electron interaction.
There is a critical distance
dcrit=√3ϵ0μ0ℏ22m2=√32ℏcm=√32¯λC,
where ¯λC is the reduced Compton wavelength of the electron, at which the two forces are equal in magnitude.
Since the Compton wavelength is a standard measure of where quantum effects start to be important, this classical analysis can't be taken too seriously. But it indicates that spin-spin interactions are important at short distances.
I wonder how these two points of view can be related.
Answer
They can be related by the fact that the Bohr radius of hydrogen is 1/α≈137 times larger than the reduced Compton wavelength of the electron. (Here α is the fine-structure constant. For helium, divide by 2 to get 68.5.) At this large a separation between the proton and electron, the magnetic interaction that I calculated is small compared to the electrostatic interaction.
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