I am having a bit of trouble with basic combinatorics pertaining to the Ising model and mean field theory. Specifically, I get that the Hamiltonian can be written
H=−J2Σi,jsisi+j−μΣisiB
Where the notation in the first sum denotes sum over all spins, i, and it nearest neigbours, indexed by j. The factor of 1/2 comes from double counting.
However then in my lectures notes, and other texts, when the mean spin is replaced by s, and the 2D nearest neighbours are explicitly put in, this somehow becomes
H=−Σisi(μB+2DJs)
But this seems to be off by a factors of 2!
If s is the mean spin, then the sum over the nearest neighbours is
Σjsi+j=2Ds
i.e. number of nearest neighbours multiplied by the mean spin. The factor of 2 then cancels with the factor of 12 in the first form of the Hamiltonian, so I get that the new Hamiltonian should be
H=−Σisi(μB+DJs) ?
Where has the factor of 2 gone?
Answer
This can be a bit confusing. But actually the Wikipedia page explains the counting fairly clearly. I prefer their notation (summing over nearest-neighbour pairs, i.e. edges of the lattice) to the double-counting notation. So the interaction term is written −J∑⟨i,j⟩sisj summing over all distinct nearest-neighbour pairs ⟨i,j⟩, so no factor 1/2. The approximation is obtained by writing si=s+(si−s) and similarly for sj. Then every pair term becomes sisj=s2+s(si−s)+s(sj−s)+(si−s)(sj−s). The approximation consists of dropping the last term. Also, all the terms in s2 are constant, and can be dropped. (Actually, more precisely, I should say that they can be taken out of the problem, and put back in again if we wish, once the value of s has been determined).
So we are left with −J∑⟨i,j⟩ssi+ssj=−2J∑⟨i,j⟩ssi. Notice that there are two terms here, not one, for every edge. Compare with eqn (1). This is where the factor of 2 comes in. Physically we are counting the fluctuation of i in the mean field provided by j, and the fluctuation of j in the mean field provided by i. The i and j terms are equivalent, of course, hence the second form of the equation. If the dimensionality is D, there are 2D edges per site i, but we take care to avoid double counting, so ∑⟨i,j⟩→122D∑i. So the result may also be written −2DJs∑isi as you have found in notes and text books.
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