According to Snell's law:
sinθt=n1n2sinθi
where θi is the incidence angle in medium 1 and (after the ray crossed the interface between medium 1 and 2) θt is the resulting angle in medium 2.
If n1>n2, there will be a critical incidence angle θc (such that sinθc=n2/n1), which causes sinθt=1. When θi>θc, sinθt is forced to be a value greater than 1, which is not achievable through a real value of θt.
Even though this angle θt has no physical meaning, which is its exact mathematical value? And is it unique?
My attempt:
Near the end of this answer, the value θ=π/2+nπ+iI (I≠0) is suggested to generate a value sinθ>1. But it seems not to be the case: in fact,
sinθ=eiθ−e−iθ2i=ei(π2+nπ+iI)−e−i(π2+nπ+iI)2i=icos(nπ)e−I+icos(nπ)eI2i=cos(nπ)coshI=(−1)ncoshI
It seems not correct. The value θ=π/2−iI seems more appropriate. In fact:
sinθ=ei(π2−iI)−e−i(π2−iI)2i=ieI+ie−I2i=coshI
and
coshI≥1,∀I∈R
So,
coshI=n1n2sinθi, I=arccosh(n1n2sinθi)
So, the initial question becomes: is this procedure correct?
Answer
Frankly, complex angles just aren't worth the hassle. As the answer you've linked to points out, they're just a complicated way to re-parametrize the evanescent wave eik⋅r=ei(kx,0,iκ)⋅(x,y,z)=eikxxe−κz as= eik(sin(θ),0,cos(θ))⋅r.
For the total-internal-reflection case that you ask about, take the form above for the evanescent wave in medium 2 for z>0, so that you're required to have k2x−κ2=k22=n22n21k21. With that notation in place, any angle that fulfills the equations k2sin(θ)=kx,1k2cos(θ)=iκ, or equivalently sin(θ)=n1n2sin(θi)cos(θ)=i√n21n22sin2(θi)−1, is an acceptable solution − so long as those two conditions are satisfied, even if you get different θs, the consequences for the real-world waveforms are exactly identical, and the θs cannot be differentiated on the basis of any physical observable. On the other hand, it's important to note that both of these conditions need to be satisfied, or you run the risk of having an incorrect sign for κ and, with that, an exponentially-increasing wave where you were meant to have a quickly-decaying evanescent wave.
To fully characterize the complex angle, let's work our conditions some more, though, by expanding out the angle into its real and imaginary parts, θ=θre+iθim (with θre,θim∈R), sin(θre)cosh(θim)+icos(θre)sinh(θim)=n1n2sin(θi)cos(θre)cosh(θim)−isin(θre)sinh(θim)=i√n21n22sin2(θi)−1, and then requiring that the real and imaginary parts of these equations be satisfied simultaneously, sin(θre)cosh(θim)=n1n2sin(θi)cos(θre)sinh(θim)=0cos(θre)cosh(θim)=0sin(θre)sinh(θim)=−√n21n22sin2(θi)−1. Since θim is real, which guarantees that cosh(θim)>0, we conclude from cos(θre)cosh(θim)=0 that cos(θre)=0 and therefore that θre=π2+nπ, n∈Z, as a necessary condition, which then implies that sin(θre)=(−1)n, so we still need to solve both of cosh(θim)=(−1)nn1n2sin(θi)sinh(θim)=−(−1)n√n21n22sin2(θi)−1. Here the second equation is always solvable, as θim=−(−1)narcsinh(√n21n22sin2(θi)−1), and this will guarantee the correct sign for κ, but the first equation is only possible if (−1)nsin(θi)>0, where you can conclude that n is even if the incidence angle is counted as positive. This is a reasonable convention, but it is not guaranteed, and a more general solution is to adjust the offset n according to the sign of the incidence angle as (−1)n=sgn(θi), giving θre=π2 (mod 2π) for θi>0, and choosing n=−1 as the principal representative for the opposite case, θre=−π2 (mod 2π) for θi<0. This means, then, that the correct solution is θre=sgn(θi)π2θim=−sgn(θi)arcsinh(√n21n22sin2(θi)−1), or in other words \theta = \mathrm{sgn}(\theta_i) \left[ \frac{\pi}{2} - i\: \mathrm{arcsinh} \mathopen{}\left(\sqrt{ \frac{n_1^2}{n_2^2}\sin^2(\theta_i)-1 }\right)\right] \mod 2\pi as the general solution.
I've phrased things like this because they're a surefire way to guarantee the correct signs, but it's clunkier than it needs to be, so it can be simplified a bit to swap that arcsinh-of-a-square-root for a simpler arccosh: to do that, start by writing \begin{align} \cosh(\theta_\mathrm{im}) & = (-1)^n\frac{n_1}{n_2}\sin(\theta_i) = \frac{n_1}{n_2}\left|\sin(\theta_i)\right| \end{align} (since the (-1)^n factor is there to guarantee positivity), allowing you to write \begin{align} \theta_\mathrm{im} = \pm \mathrm{arccosh} \mathopen{}\left(\frac{n_1}{n_2}\left|\sin(\theta_i)\right|\right) \end{align} up to a sign ambiguity which we've resolved above. With the sign resolution from above, though, we get as our final result \theta = \mathrm{sgn}(\theta_i) \left[ \frac{\pi}{2} - i\: \mathrm{arccosh} \mathopen{}\left(\frac{n_1}{n_2}\left|\sin(\theta_i)\right|\right)\right] \mod 2\pi .
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