As often stated in books, near a phase transition we may express the free energy density as a power series in the order parameter ϕ(r). Up to quartic contributions, we have f=f0−hϕ(r)+a2ϕ(r)2+12|∇ϕ(r)|2+a3ϕ(r)3+a4ϕ(r)4
Now, I'm a bit confused about a few things:
The terms with coefficients ai make sense to me - if we do a Taylor series we get a polynomial. However, why can't we include a term a1ϕ(r)?
The external field term sort of makes sense, but this doesn't really stem from a power series does it? It's just something we put in by hand.
Where does the gradient term come from? Is this also put in by hand - I don't see how this could come from a power series... And, why does it have to have coefficient 12? Why can't we use |∇ϕ(r)| and higher powers?
If anyone has any input on these points, or can suggest a good source of explanation, that would be useful :)
No comments:
Post a Comment