The matrix elements of the momentum operator in position representation are:
⟨x|ˆp|x′⟩=−iℏ∂δ(x−x′)∂x
Does this imply that ⟨x|ˆp|x′⟩=0 whenever x≠x′?
Is the momentum operator diagonal in position representation?
I know that the momentum operator shouldn't be diagonal in position representation (otherwise solving for the eigenergies and eigenfunctions of most Hamiltonians would be trivial). I am obviously confused here. I need more than just yes/no answers to these questions. I need some explanation, or some intuition.
Answer
There is a heuristic way to look at this.
The Dirac delta function corresponds to a spike when its argument is zero. You can view it as the limit of a sequence of Gaussian functions whose areas are all one but whose width goes to zero. The derivative of a Gaussian function looks like this:
So in the limit, the derivative of the Dirac function is something like an up spike infinitesimally to the left of the origin followed by a down spike infinitesimally to the right. So the matrix elements you're looking at aren't actually diagonal, they're infinitesimally off-diagonal.
These kinds of heuristics can be useful, but they can also be dangerous, so don't take what I say too literally.
Update: Another way to look at this is to approach the derivative Dirac delta via a discretisation. If the wavefunction is represented by a vector of equally spaced samples, the derivative can be represented by central differences. Assuming periodic boundary conditions we get a matrix like:
12(0100…−1−1010…00−101…000−10…0⋮1000…0)
We have 1's just above the diagonal and -1's just below. As the discretisation gets finer we get a matrix where they entries are more and more concentrated near the diagonal even though all of the non-zero terms are actually off-diagonal. In the limit you can again imagine something that is infinitesimally off-diagonal.
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