Consider the Lie algebra of SU(2).
To find the infinitesimal generators we linearise about the identity U=I+iαT
But instead linearising as U=I+αT
Answer
The factor of i is generally a matter of convention. Essentially, it boils down to choosing what constant you'd like sitting in front of the defining equation,
[Ta,Tb]=fabcTc
of the structure constants fabc of the Lie group. We could have instead a factor of i or any constant in our definition and it is a matter of convention.
There is also some freedom in choosing the normalisation of the 'inner product' Tr(TaTb) though there are restrictions depending on if the group is compact for instance.
In my own experience, physicsts keep a factor of i explicit and in the mathematical literature it is usually omitted.
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