Wednesday, 22 May 2019

Which derivative with respect to time is which in the Heisenberg picture of quantum mechanics?


For an observable $A$ and a Hamiltonian $H$, Wikipedia gives the time evolution equation for $A(t) = e^{iHt/\hbar} A e^{-iHt/\hbar}$ in the Heisenberg picture as


$$\frac{d}{dt} A(t) = \frac{i}{\hbar} [H, A] + \frac{\partial A}{\partial t}.$$


From their derivation it sure looks like $\frac{\partial A}{\partial t}$ is supposed to be the derivative of the original operator $A$ with respect to $t$ and $\frac{d}{dt} A(t)$ is the derivative of the transformed operator. However, the Wikipedia derivation then goes on to say that $\frac{\partial A}{\partial t}$ is the derivative with respect to time of the transformed operator. But if that's true, then what does $\frac{d}{dt} A(t)$ mean? Or is that just a mistake?


(I need to know which term to get rid of if $A$ is time-independent in the Schrodinger picture. I think it's $\frac{\partial A}{\partial t}$ but you can never be too sure of these things.)



Answer



There is no mistake on the Wikipedia page and all the equations and statements are consistent with each other. In $$A_{\rm Heis.}(t) = e^{iHt/\hbar} A e^{-iHt/\hbar}$$ the letter $A$ in the middle of the product represents the Schrödinger picture operator $A = A_{\rm Schr.}$ that is not evolving with time because in the Schrödinger picture, the dynamical evolution is guaranteed by the evolution of the state vector $|\psi\rangle$.



However, this doesn't mean that the time derivative $dA_{\rm Schr.}/dt=0$. Instead, we have $$ \frac{dA_{\rm Schr.}}{dt} = \frac{\partial A_{\rm Schr.}}{\partial t} $$ Here, $A_{\rm Schr.}$ is meant to be a function of $x_i, p_j$, and $t$. In most cases, there is no dependence of the Schrödinger picture operators on $t$ - which we call an "explicit dependence" - but it is possible to consider a more general case in which this explicit dependence does exist (some terms in the energy, e.g. the electrostatic energy in an external field, may be naturally time-dependent).


In Schrödinger's picture, $dx_{i,\rm Schr.}/dt=0$ and $dp_{j,\rm Schr.}/dt=0$ which is why the total derivative of $A_{\rm Schr.}$ with respect to time is given just by the partial derivative with respect to time. Imagine, for example, $$ A_{\rm Schr.}(t) = c_1 x^2 + c_2 p^2 + c_3 (t) (xp+px) $$ We would have $$ \frac{dA_{\rm Schr.}(t)}{dt} = \frac{\partial c_3(t)}{\partial t} (xp+px).$$ These Schrödinger's picture operators are called "untransformed" on that Wikipedia page. The transformed ones are the Heisenberg picture operators given by $$A_{\rm Heis.}(t) = e^{iHt/\hbar} A_{\rm Schr.}(t) e^{-iHt/\hbar}$$ Their time derivative, $dA_{\rm Heis.}(t)/dt$, is more complicated. An easy differentiation gives exactly the formula involving $[H,A_{\rm Heis.}]$ that you quoted as well. $$\frac{d}{dt} A_{\rm Heis.}(t) = \frac{i}{\hbar} [H, A_{\rm Heis.}(t)] + \frac{\partial A_{\rm Heis.}(t)}{\partial t}.$$ The two terms in the commutator arise from the $t$-derivatives of the two exponentials in the formula for the Heisenberg $A_{\rm Heis.}(t)$ while the partial derivative arises from $dA_{\rm Schr.}/dt$ we have always had. (These simple equations remain this simple even for a time-dependent $A_{\rm Schr.}$; however, we have to assume that the total $H$ is time-independent, otherwise all the equations would get more complicated.) The two exponentials on both sides never disappear by any kind of derivative, so obviously, all the appearances of $A$ in the differential equation above are $A_{\rm Heis.}$. The displayed equation above is the (only) dynamical equation for the Heisenberg picture so it is self-contained and doesn't include any objects from other pictures.


In the Heisenberg picture, it is no longer the case that $dx_{\rm Heis.}(t)/dt=0$ (not!) and the similar identity fails for $p_{\rm Heis.}(t)$ as well. $A_{\rm Heis.}(t)$ is a general function of all the basic operators $x_{i,\rm Heis.}(t)$ and $p_{j,\rm Heis.}(t)$, as well as time $t$.


No comments:

Post a Comment

Understanding Stagnation point in pitot fluid

What is stagnation point in fluid mechanics. At the open end of the pitot tube the velocity of the fluid becomes zero.But that should result...