Saturday 13 September 2014

solid state physics - Electron density in metals at non zero temperature


When computing the electron density in metals, the usual crude result is computed for zero temperature. That is, we integrate


\begin{equation} n=\frac{8\sqrt{2}\pi m^{3/2}}{h^{3}} \int\limits_{0}^{E_{F}}\sqrt{E} dE = \frac{8\sqrt{2}\pi m^{3/2}}{h^{3}} \left ( \frac{2}{3}E_{F}^{3/2} \right ) . \end{equation}


I am looking for an electron density estimate for non zero temperatures, but I can't deal with following integration:


$$ n=\frac{8\sqrt{2}\pi m^{3/2}}{h^{3}} \int\limits_{0}^{\infty}\frac{\sqrt{E}}{1+\exp(\frac{E-E_{F}}{k_{B}T})} dE . $$


Can you help me with a link where this problem is solved? Or simply a term which describes (approximates) the electron density for higher temperatures. Is there some "rule of thumb" for the metals - e.g. some sort of exponential dependence. Does the derivation need more precise approach? Thank you :)



Answer



The thing you are looking for is called the Sommerfeld Expansion. The integral you specify can be approximated quite well to calculate the chemical potential (different to $E_F$ when the electrons are not completely degenerate) and expressions for the number density and energy density of the electrons when the chemical potential (or $E_F$) is larger than $kT$, but the gas is not completely degenerate.


Often the expansion is limited to the first two terms; the second term is of order $(kT/E_F)^2$, while the third term is neglected as becoming small when $(kT/E_F)^4$ is small.



Full details can be found at the wikipedia link, but also a quick search turned up this student paper from a Graz Univ course on Advanced Solid State Physics. It seems to provide a very clear description, and derives the expressions you want for 1, 2 and 3D Fermi-Dirac gases.


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