To my understanding the work done on an object is defined mathematically as: W=→F⋅→S=|→F||→S|cosθ
There has to be something wrong with my reasoning, but what is it?
Answer
Because it's not any work, but the work done by a force that produces a displacement.
In the scenario you describe, somehow that force is not doing any work on the particle. This could be because the particle is restricted by another force to not go perpendicular and then the sum of forces in the perpendicular direction is zero.
In the second scenario, with the box and the normal force, it's the same. That force doesn't do any work since in the direction of that force there is zero movement. Which is analogous to say that the cosine of the angle between the displacement and such force is 90°.
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