I've been studying quantum theory for a while now and have a number of closely related questions that are not giving me any peace. I am not sure if such a long format is appropriate here, but I'd like to seize this opportunity and share my questions on this wonderful website.
One thing I'm trying to do in order to have a better understanding of the QFT, is to apply the formalism of occupation numbers to the lowest possible numbers of identical particles in the system. Such formalism is based on the usage of the wave vectors ('Fock states', 'second-quantised states') of the form |n1,n2,...,nk,...⟩,
If we set ℏ=ω=1 and ignore the vacuum energy ℏω/2, the Hamiltonian takes the form of ˆH=ˆa†ˆa,
The correspondence between the second-quantised states and the eigenfunctions of the Hamiltonian is: |0⟩≡|0,0,0,...⟩,|1⟩≡|11,0,0,...⟩,|2⟩≡|0,12,0,...⟩,|3⟩≡|0,0,13,...⟩.
This construction may look pretty unusual. To better understand the rules of the game, employ the matrix formalism: ˆa†≅(0000⋯√1000⋯0√200⋯00√30⋯⋮⋮⋮⋮⋱),ˆa≅(0√100⋯00√20⋯000√3⋯0000⋯⋮⋮⋮⋮⋱),|0⟩≅(1000⋮).
Now one can easily guess the form of the operators which obey the desired requirements: ˆa†1≅(0000⋯1000⋯0000⋯0000⋯⋮⋮⋮⋮⋱),ˆa†2≅(0000⋯0000⋯0100⋯0000⋯⋮⋮⋮⋮⋱),ˆa†3≅(0000⋯0000⋯0000⋯0010⋯⋮⋮⋮⋮⋱).
With the use of those operators, one can immediately write the Hamiltonian of a single harmonic oscillator in the 'QFT form': ˆH=∞∑k=1ωkˆa†kˆak,ωk=k.
Regarding the operators ˆa†k. First of all, they turn out to be nilpotent. Second, we have now some issues with the commutation relations which we have never discussed so far. Of course, we would prefer the newly constructed operators to obey the standard Heisenberg commutation relations [ˆa,ˆa†]=1.
By the end of the day, we can say that:
1. We managed to construct the operators defined through ˆak|n1,n2,...,nk,...⟩=√nk|n1,n2,...,nk−1,...⟩,ˆak|n1,n2,...,nk,...⟩=√nk+1|n1,n2,...,nk+1,...⟩.
2. Those operators only obeyed the Heisenberg commutation relations when sandwiched by the vacuum states.
QUESTION 1. Does everything look correct so far?
Now, let's try to make a step further and extend the construction to a system of two identical particles. First of all, at this point one should stop thinking of one-particle states as of eigenstates of the Hamiltonian. Such basis would be inconvenient due to the issues with the degeneracy. It's better to think of the |k⟩ states as of states with definite momentum or position. Then, the one-particle Hamiltonian writes as: ˆH1=∫|k⟩Hkm⟨m|dkdm.
The Fock space of the two-particle system is the symmetrised tensor product of two one-particle spaces. The basis vectors are now defined as: |0,0,0,...⟩≡|0⟩⊗|0⟩≡|0⟩,|1k⟩≡1√2(|0⟩⊗|k⟩+|k⟩⊗|0⟩),|1k,1m⟩≡1√2(|k⟩⊗|m⟩+|m⟩⊗|k⟩),|2k⟩≡|k⟩⊗|k⟩.
From now, we will denote the one-particle operators by (j)ˆa†k: (1)ˆa†k|0⟩≡((1)ˆa†k⊗ˆ1)|0⟩≡|k⟩⊗|0⟩,(2)ˆa†k|0⟩≡(ˆ1⊗(2)ˆa†k)|0⟩=|0⟩⊗|k⟩.
We define the operators ˆa†k and ˆak by their action on the basis vectors in the following way: ˆa†k|0⟩=|1k⟩,ˆak|...,0k,...⟩=0,ˆa†k|1⟩=2|2k⟩.
QUESTION 2. How to express these operators in terms of one-particle operators? I.e. in the form: ∑kαk(1)ˆAk⊗(1)ˆBk.
I think, in principle this should be possible, since the tensor product of bases of the spaces of operators should form a basis in the space of operators acting in the tensor product vector space. More precisely, if any two linear operators (1)ˆA and (1)ˆB can be written in the form (1)ˆA=∑i,jAij(1)ˆeij,(2)ˆB=∑k,lBkl(2)ˆekl,
It seems natural to suggest something like ˜a†k=α((1)ˆa†k⊗ˆ1+ˆ1⊗(2)ˆa†k).
Good news is that if we simply follow the definitions of ˆa†k and ˆak above (the ones through the action on the basis vectors), the commutation relations are, of course, satisfied: ⟨0|[ˆak,ˆa†k]|0⟩=1,⟨1k|[ˆak,ˆa†k]|1k⟩=1,⟨2k|[ˆak,ˆa†k]|2k⟩=?.
Now let me explain why all these questions arise. Basically, I'm not satisfied with the process of canonical quantisation of the fields. When quantising the field mode by mode, people formally perform same operation as in the case of harmonic oscillator. However, the meaning we give for the results is quite different.
Let's first ask ourselves why we call the 5th energy state of harmonic oscillator ''the particle with energy 5ℏω/2'', not ''the five-particle state''. Is it just a matter of convention? What stops us from using one-particle QM for describing the motion of few particles?
We all we told that to some extent it makes sense to treat the particle as a Gaussian wave packet. Let |ψ(x,t)⟩=|g(x−x0−vgroupt)⟩
Why do we say that such wave vector corresponds to a single particle? From the theoretical point of view it's because we have started with the classical system of just a single particle. The more interesting is experimental approach. After the measurement, the wave function collapses and forgets about both 'separate' Gaussians. Had we set two detectors in the different spacial points, only one of them would observe the particle (this is basically the double slit experiment). That's why we treat the excited states of harmonic of harmonic oscillator (the potential actually does not play any role) as different energy levels of a single particle, but not as multi-particle state.
Now, let's perform first few steps of the field quantisation. For simplicity, let's use Klein-Gordon field. Even though it can be thoght of as a quantum-mechanical Schrödinger field in one-particle formalism (despite some problems with the negative energies, e.g. see Davydov), the trick is to consider it first as a classical wave equation. (∂μ∂μ+m2)ϕ(x)=0.
We have already discussed that, in case of the harmonic oscillator, the states |n⟩ cannot be treated as multi-particle states; one necessarily should call them the excited states of a single particle.
Nevertheless, in QFT we treat the state 12(ˆa†→p)2|0⟩ as a two-particle state! 12(ˆa†→p)2|0⟩=|2→p⟩,
QUESTION 3. In QFT, why do we treat those excitations as multi-particle states?
Again, let me try to find an answer myself. In reality, the procedure of the field quantisation is a kind of a formal trick. A more rigorous approach is to consider the large number N of particles in the Schrödinger formalism (they same way we did with two particles) and then take the limit~N→∞.
This approach is often considered old-school. It's poorly explained in Landau-Lifshitz, but also in great detail in 'Quantum Mechanics' by Blokhintsev. It requires few steps:
1. Determine the action of the multi-particle Hamiltonitan ˆH=N∑m=1ˆHm
2. Define the the creation and annihilation operators by their action on those states: ˆak|n1,n2,...,nk,...⟩=√nk|n1,n2,...,nk−1,...⟩,ˆak|n1,n2,...,nk,...⟩=√nk+1|n1,n2,...,nk+1,...⟩.
3. Show that the Hamiltonian can be nicely written in terms of creation and annihilation operators acting on the multi-particle states in the usual manner. ˆH=∑m,nHmnˆa†mˆan+...,
The final expression for the Hamiltonian is same as in the case of replacing the classical fields by their 'second-quantised' versions. The particular reason why I like this approach is because it allows us to avoid using two most questionable assumptions of the canonical field quantisation:
∙''Let's treat the Schrödinger / Klein-Gordon / ... ~ field as a classical field and the quantise its Fourier modes...''
∙ ''Let's treat the excitations of quantised Fourier modes as multi-particle states...''
Instead, we define the creation operators by their action on vacuum and postulate that they create a symmetrised state in the multi-particle system.
One may wonder how this approach should work in EM, since in that case we have a field already at the classical level. Here is my guess formulated as a question.
QUESTION 4. Can we 'second-quantise' the EM field by treating the Maxwell equations as a Schrödinger equation (e.g. see books by Fushchich and Nikitin) and then considering the multi-particle states of those?
I guess, the typical conclusion people make after thinking on such topics is: ''Well, both approaches (symmetrising single-particle states and quantising the Fourier modes) should work; both have various pros and cons; the field quantisation if more useful because it leads us to the correct answer faster (so that we could finally dive into calculating the amplitudes and cross-sections).''
Finally, I would like to ask my most serious question, the one which bothered me for years, and which is perfectly illustrated by the Coleman's 'missing box method' illustration (from his Physics 253a lectures). One way to go from classical mechanics to field theory, through the 'QM' box, is: Quantise theclassical systemin a usual way→Take many copiesof such systemsand constructsymmetrised states→→Define creationand annihilationoperators byaction on those states→Express theHamiltonian inin terms ofsuch operators
QUESTION 5. Why are the two procedures equivalent and lead to the same result?
More precisely, why do we end up with same Fock spaces, same creation and annihilation operators?
I know, all ingredients are right here, in front of me... but still cannot collect the puzzle. And I am not satisfied with a simple comparison of the outputs of two black boxes.
Any ideas or references to various sources will be greatly appreciated.
Many thanks!
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