If we have the polarization of the electric field in the z direction then we have the selection rule that: Δm=0
What is the physical reason behind this rule?
Since if the emitted photon travels along the z-axis we must have Δm=±1 does this mean that we a photon cannot be emitted in the direction of the polarization of the electric field?
Answer
A linearly polarized photon is an eigenstate of angular momentum m=0 along the polarization direction. That succinctly explains the selection rule. In your question, you make the error of assuming that the propagation direction and the polarization are both along z. In fact, this is impossible, since electromagnetic waves are transverse. If the the electric field direction is along z, then the propagation direction lies in the xy-plane. For concreteness, let us say the propagation is along x. Then the linearly polarized wave is an equal superposition of mx=1 and mx=−1 circular polarization states; the superposition of these angular momentum states is exactly an mz=0 state.
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