The Setup
Let Greek indices be summed over $0,1,\dots, d$ and Latin indices over $1,2,\dots, d$. Consider a vector potential $A_\mu$ on $\mathbb R^{d,1}$ defined to gauge transform as $$ A_\mu\to A_\mu'=A_\mu+\partial_\mu\theta $$ for some real-valued function $\theta$ on $\mathbb R^{d,1}$. The usual claim about Coulomb gauge fixing is that the condition $$ \partial^i A_i = 0 $$ serves to fix the gauge in the sense that $\partial^iA_i' = 0$ only if $\theta = 0$. The usual argument for this (as far as I am aware) is that $\partial^i A'_i =\partial^iA_i + \partial^i\partial_i\theta$, so the Coulomb gauge conditions on $A_\mu$ and $A_\mu'$ give $\partial^i\partial_i\theta=0$, but the only sufficiently smooth, normalizable (Lesbegue-integrable?) solution to this (Laplace's) equation on $\mathbb R^d$ is $\theta(t,\vec x)=0$ for all $\vec x\in\mathbb R^d$.
My Question
What, if any, is the physical justification for the smoothness and normalizability constraints on the gauge function $\theta$?
EDIT 01/26/2013 Motivated by some of the comments, I'd like to add the following question: are there physically interesting examples in which the gauge function $\theta$ fails to be smooth and/or normalizable? References with more details would be appreciated. Lubos mentioned that perhaps monopoles or solitons could be involved in such cases; I'd like to know more!
Cheers!
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