Optical density is a measure of the refracting power of a medium. In other words, the higher the optical density, the more the light will be refracted or slowed down as it moves through the medium. Optical density is related to refractive index in that materials with a high refractive index will also have a high optical density. Light will travel slower through a medium with a high refractive index and high optical density and faster through a medium which has a low refractive index and a low optical density. So to restate the question, why do optical media have different refractive indices?
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