Thursday, 14 December 2017

quantum mechanics - Why do electrons absorb and re-emit photons?



Up to a certain time, I was told photons a.k.a. light was just a wave of energy. Then I was told, no, light is actually a particle. And electrons in an atom absorb and re-emit it. But why do electrons bother to absorb and re-emit light and not just let it pass all the time? (An electron would also be unstable by absorbing the energy and thus it re-emits it but in the first place why does it absorb it?)


*Note:- A similar question was asked earlier (How does an electron absorb or emit light?) but my question is not the same. The earlier asked question was how does it happen and I ask why does it happen.



Answer




And electrons in an atom absorb and re-emit it. But why do electrons bother to absorb and re-emit light and not just let it pass all the time?



There is a basic misunderstanding in your question.


An electron is an elementary particle of fixed mass. It can scatter off a photon, (which is also an elementary particle); if accelerated it can emit a photon, but it does not absorb it, because the electron's mass is fixed, and if it were able to absorb a photon - at the electron's center of mass - the mass would have to change, which contradicts observations and special relativity for elementary particles.


The terms absorption and absorbs are not usable with free electrons. It is the bound electrons in an atomic system, which may change energy levels in the atom when the atom absorbs a photon. So it is not the electron that absorbs the photon, but the atom.


The atom has energy levels, and if the photon energy coincides (within a small $ΔE$, the width of the energy level) with the transition energy of kicking an electron to an empty energy level, then the atom can absorb the photon (not the electron). So the answer to "why", above, is "because the photon has the appropriate energy to transfer the electron to an empty energy level".



If the photon energy does not coincide with transition energy of the atom, the photon may scatter with the spillover electric fields of the atom or molecule either elastically, or transferring energy and a lower energy photon continues on its way.


The relevant thought to keep is that an elementary particle cannot absorb a photon. Composite ones as atoms, molecules and lattices, can.


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