It is my understanding that metals are a crystal lattice of ions, held together by delocalized electrons, which move freely through the lattice (and conduct electricity, heat, etc.).
If two pieces of the same metal are touched together, why don't they bond?
It seems to me the delocalized electrons would move from one metal to the other, and extend the bond, holding the two pieces together. If the electrons don't move freely from one piece to the other, why would this not happen when a current is applied (through the two pieces)?
Answer
I think that mere touching does not bring the surfaces close enough. The surface of a metal is not perfect usually. Maybe it has an oxide layer that resists any kind of reaction. If the metal is extremely pure and if you bring two pieces of it extremely close together, then they will join together. It's also called cold welding.
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