Saturday 27 February 2016

What is the meaning of internal Energy?


What is the meaning of internal energy. Is it the amount of energy that a body contains?



Answer



Standard Definition : The internal energy of a system is identified with the random, disordered motion of molecules; the total (internal) energy in a system includes potential and kinetic energy.


Since this molecular motion is primarily a function of temperature, the internal energy is sometimes called 'thermal energy'.


Total energy of the system $(E)$ = U (Thermal energy) + $E_{Kinetic\space of\space system}$ + $E_{Potential\space of\space system}$ ....



Here, the two terms viz, $E_{Kinetic\space of\space system}$ and $E_{Potential\space of\space system}$, are for the system and not the particles inside the system. For the particles the $KE$ and $PE$ is included in the internal energy.


In most of the cases, kinetic energy, potential energy, chemical energy of the system is constant, thus we conclude,


$\Delta{E}=\Delta{U}$


The proper form of the first law of thermodynamics is given by,


$\Delta E = q + W$,


but for the reasons stated above,


$\Delta U = q + W$.


Therefore, summing it up, Internal energy includes :


1). Translational KE


2). Vibrational and rotational kinetic energy



3). Potential energy from intermolecular forces


No comments:

Post a Comment

Understanding Stagnation point in pitot fluid

What is stagnation point in fluid mechanics. At the open end of the pitot tube the velocity of the fluid becomes zero.But that should result...