Thursday 20 November 2014

definition - Which one true in First law of thermodynamics: $Q = Delta U pm W = Delta U pm pDelta V$ or $Delta U= Delta Q + Delta W $?


Which one true in First law of thermodynamics:





  1. $Q = \Delta U \pm W = \Delta U \pm p\Delta V$? (where $\Delta U$ is change of internal energy, $W$ work made by system and $Q=cm\Delta T $ heat made by system.)




  2. or $\Delta U= \Delta Q + \Delta W $? (where $\Delta U$ is change of internal energy, $W$ work made by system and $Q=cm\Delta T $ heat made by system.)




First one from one the finnish physics texbook another is from here.



Answer




It is pretty much a matter of convention regarding who is doing work on whom. For me the most conceptually clear picture is the wikipedia version, $$\Delta U=\Delta Q+\Delta W,$$ i.e., that the change in the internal energy of the system equals the heat delivered to it plus the work performed on the system. (Note, however, the difference from what you quote!) If one takes $\Delta W$ to be the work performed by the system then its sign will change, but this does not of course change the physical content of the law. If in doubt, put it in words! Once you're clear on what each symbol means the signs will follow automatically.


A couple of caveats, though: note that $Q$ as such is a misleading term. One can only assign heat quantities to processes, which is emphasized by the notation $\Delta Q$.


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