Monday, 10 November 2014

quantum mechanics - What is a Hilbert Space?


The Hilbert Space is the space where wavefunction live. But how would I describe it in words? Would it be something like:




The infinite dimensional vector space consisting of all functions of position $\psi(\vec x)$ given the conditions that $\psi(\vec x)$ is a smooth, continuous function.



(I am not saying this is right, it is merely an example). Further more how does $\Psi(\vec x, t)$ fit into this? Would it be appropriate to say that at any $\Psi(\vec x, t)$ itself is not in the Hilbert space, but at any given time $t_0$ then the function $\psi_0 (\vec x)\equiv \Psi(\vec X,t_0)$ is a member of the Hilbert Space? And all operators $\hat Q$ have to act on members in the Hilbert Space and therefore cannot have time-derivatives but can have time dependencies.



Answer



Your idea of what $\psi(\vec x,t)$ is supposed to be is essentially correct. Given a space of states $\mathcal{H}$, the "Schrödinger state" is a map $$ \psi : \mathbb{R}\to\mathcal{H}, t\mapsto\lvert\psi(t)\rangle$$ where $\lvert \psi(t)\rangle\in\mathcal{H}$ for every instant $t$. If $\mathcal{H}$ is a space of functions in a variable $\vec x$, then $\lvert \psi(t)\rangle$ is often written $\psi(\vec x,t)$.


The space of wavefunctions in usual quantum mechanics is crucially not the space of smooth functions $C^\infty(\mathbb{R}^3,\mathbb{C})$, but the space of equivalence classes of square integrable functions $L^2(\mathbb{R^3},\mathbb{C})$(link to Wikipedia article on $L^p$-spaces). This space contains the smooth compactly supported functions $C_c^\infty(\mathbb{R}^3,\mathbb{C})$ (non-compactly supported functions are not necessarily square-integrable) and also all smooth square-integrable functions, but is larger.


The reason for this is twofold: For one, there is no reason to demand a generic wavefunction be continuous - the whole physical content of the wavefunction is encapsulated in the probability density $$ \rho(\vec x) = \lvert\psi(x)\rvert^2$$ and this needs to have $\int\rho(\vec x)\mathrm{d}^3x = 1$ to be probability density, hence $\psi$ must be square integrable, but nothing else.


Another reason is that the smooth compactly supported functions do not form a Hilbert space under the scalar product $$ (f,g) = \int \overline{f(x)}g(x)\mathrm{d}^3 x$$ since they are not complete - there are sequences which are Cauchy with respect to the $L^2$-norm induced by this inner product, but which do not converge. The space of square-integrable functions is precisely the completion of the smooth compactly supported functions under this norm, and hence a Hilbert space. In other words, every wavefunction may be arbitrarily accurately be approximated by a smooth compactly supported function, but is itself not guaranteed to be a smooth function.


Among other difficulties commonly overlooked, this means that, strictly speaking, one cannot evaluate wavefunctions at points, since the $L^2$-space elements are only defined up to a zero measure set, and points are of zero measure. This is again meaningful when considering $\rho(\vec x)$: The value of a probability density on a zero measure set is physically meaningless, since only the integration of it over a set of non-zero measure gives a physically relevant probability.



No comments:

Post a Comment

Understanding Stagnation point in pitot fluid

What is stagnation point in fluid mechanics. At the open end of the pitot tube the velocity of the fluid becomes zero.But that should result...