For the potential term in the Hamiltonian, I understand that we go through the same process as with the kinetic energy term. On the RHS of the TDSE, we get something like 12∑i∑j≠i∑k∑l≠k⟨ij|V|kl⟩C(…Ei−1EkEi+1…Ej−1ElEj+1…;t).
Reordering the argument list of C(…) on the RHS incurs a phase factor of (−1)P, where P depends on the order of i,j,k,l.
Some examples: if their order of ascent is ...
kilj: P=nk+1+⋯+ni−1+nl+1+⋯+nj−1
klij: P=nk+1+⋯+ni−1+nl+1+⋯+nj−1
likj: P=ni+1+⋯+nk−1+nl+1+⋯+nj−1+1 [the extra +1 comes from the fact that i and j are positioned with opposite 'polarity' to k and l, therefore the Ek,El have to be swapped past each other to get into the correct positions]
As above, by my reckoning, P(klij)=P(kilj), however if we calculate (−1)P by operating on |{nm}⟩ like a†ia†jalak|{nm}⟩, I get (−1)Sk+Sl−1+Sj−2+Si−2|…nk−1…nl−1…nj+1…ni+1⟩=(−1)Sk+Sl+Sj+Si−1|…nk−1…nl−1…nj+1…ni+1…⟩
if the order is klij but
(−1)Sk+Sl−1+Sj−2+Si−1|…nk−1…nl−1…nj+1…ni+1…⟩=(−1)Sk+Sl+Sj+Si|…nk−1…nl−1…nj+1…ni+1…⟩
if the order is kilj. The order of i and l seems to matter when I calculate the phase factor by successive application of the a,a† but not when I calculate it by reordering the arguments of the C(…) coefficients. Where am I going wrong?
Answer
Worked out where I've been going wrong. Referring to the content of my question, in the klij case, i.e. $k
P(klij)=nk+1+⋯+ni−1+⋯+nl+1+⋯+nj−1−1=Si−Sk−nk+Sj−Sl−nl−1
and so the phase factor, (−1)P(klij)=(−1)Si+Sk−nk+Sj+Sl−nl−1, which, with the δnk0δnl0 on the RHS, gives (−1)Si+Sk+Sj+Sl−1. This is the same phase factor you get when you operate on the state like a†ia†jalak|{nm}⟩ as I mentioned in the original question.
No comments:
Post a Comment