Tuesday, 28 June 2016

homework and exercises - Adiabatic expansion in van der Waals gas




Given a Van der Waals gas with state equation: (P+N2aV2)(VNb)=NkT,

show that the equation of an adiabatic process is: (VNb)TCV=constant.


I began by setting đQ=0 in dU=đQ+đW,

one then gets 0=dU+P dV.


Now given U=32NkTN2aV, I plugged it's derivatives into dU=(UT)V dT+(UV)T dV,

from which I obtained 0=CV dt+(P+N2aV2)T dV=CV dT+NkTVNb dV,
using V đW's equation.


Dividing by T and integrating gives C=logTCV+log(VNb)Nk,

which is equivalent to C=(VNb)NkTCV,
for C and C constants.


Now the expression so obtained seems very similar to what I was looking for, but I can't seem to get rid of the Nk exponent. Anyone got a different approach to this problem, or a way to get the desired formula?



Answer



The correct answer is (VNb)TCV/Nk=const, the problem statement is just wrong.


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