The change of entropy is defined ΔS=∫dQrevT. If a system is isolated the heat transfer between the system and the surroundings is zero (dQ=0), thus ΔS=0.
However, it is commonly stated that the entropy of an isolated system can increase. How is this possible, given the above definition of entropy?
Answer
The definition of entropy dS=δQT only applies for reversible processes. For every irreversible process, dS>δQT. Therefore, if the sytem is isolated (δQ=0), and an irreversible process occurs, dS>0.
Simple irreversible processes include friction, mixing, and heat transfer accross a finite temperature difference.
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