Sunday, 3 January 2016

thermodynamics - How does the entropy of an isolated system increase?


The change of entropy is defined ΔS=dQrevT. If a system is isolated the heat transfer between the system and the surroundings is zero (dQ=0), thus ΔS=0.


However, it is commonly stated that the entropy of an isolated system can increase. How is this possible, given the above definition of entropy?



Answer



The definition of entropy dS=δQT only applies for reversible processes. For every irreversible process, dS>δQT. Therefore, if the sytem is isolated (δQ=0), and an irreversible process occurs, dS>0.


Simple irreversible processes include friction, mixing, and heat transfer accross a finite temperature difference.


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